2. Materials and methods.
2.1. Study area and sample collection
TLR originates from the West Lake and runs through Hanoi inner city before merging with Kim Nguu River downstream and
flowing into Nhue River. It has a length of 14 km and covers the basin of 77.5 square kilometers, which is the largest drainage
catchment in Hanoi. The total amount of wastewater discharged into TLR is approximately 290,000m
3
per day [9]. The drainage
network in the TLR basin was built to collect wastewater both from the ancient city, where there are no new construction activities
and in the new urban areas, where the infrastructure is still being completed.
Figure 1. Sampling sites along TLR basin in Hanoi, Vietnam
S1: Buoi Discharger; S2: Dichvong Bridge; S3: Caugiay Bridge; S4: Cot Bridge; S5: Trunghoa Bridge; S6: Moc Bridge; S7: Moi
Bridge.
Sampling locations of sediment and sludge were illustrated in Fig. 1. Sediment samples were collected from seven points
near the crossing bridges along 7-km TLR upstream which receives wastewater and storm water from the main sewers. Two targeted
sewers in this study were Tran Binh Trong (TBT) sewer from the old urban area and Thai Ha (TH) sewer from the new urban area.
TBT sewer was built by French during the French colonial period while Thai Ha sluice was built in 1985, during the Renovation
period. These two 600-meter sewers have been built in different stages of the Hanoi drainage network, making them representative to
others sewers which were built at the same period. Sewerage sludge was collected from six manholes consisting in the sewer.
Sewage sludge was collected in the rainy season (June, 2016) and another time in dry season 2017 (January, 2017) while the
sediment samples were collected in November, 2016. Sludge samples were collected and preserved in accordance with current
Vietnamese technical standards including TCVN 6663 - 3:2008 - Water quality - Sampling - Part 3: Guidance on the preservation
and handling of water samples (ISO 5667-12:1995 Part 12: Guidance on sampling of bottom sediments) and TCVN 6663 - 15: 2004
(ISO 5667-15: 1999) Water quality - Sampling - Part 15: Guidance on preservation and handling of sludge and sediment samples.
Particularly, sediment samples were taken by buckets at the depth of 10-30 cm, then placed in 250 mL plastic bags, stored in dark
1km
Figure 1. Sampling sites along TLR basin in Hanoi, Vietnam
S1: Buoi Discharger; S2: Dichvong Bridge; S3: Caugiay Bridge; S4: Cot Bridge;
S5: Trunghoa Bridge; S6: Moc Bridge; S7: Moi Bridge
(TBT) sewer from the old urban area and Thai Ha (TH) sewer from the new urban area. TBT sewer
was built by French during the French colonial period while Thai Ha sluice was built in 1985, during
the Renovation period. These two 600-meter sewers have been built in di
fferent stages of the Hanoi
drainage network, making them representative to others sewers which were built at the same period.
Sewerage sludge was collected from six manholes consisting in the sewer.
Sewage sludge was collected in the rainy season (June, 2016) and another time in dry season 2017
(January, 2017) while the sediment samples were collected in November, 2016. Sludge samples were
collected and preserved in accordance with current Vietnamese technical standards including TCVN
6663 - 3:2008 - Water quality - Sampling - Part 3: Guidance on the preservation and handling of
water samples (ISO 5667-12:1995 Part 12: Guidance on sampling of bottom sediments) and TCVN
6663 - 15: 2004 (ISO 5667-15: 1999) Water quality - Sampling - Part 15: Guidance on preservation
and handling of sludge and sediment samples. Particularly, sediment samples were taken by buckets
at the depth of 10-30 cm, then placed in 250 mL plastic bags, stored in dark box at two to five degree
Celsius [
14
,
15
]. The preservation time for analysis parameters were in accordance with the above
Vietnamese technical standards [
14
,
15
].
2.2. Sample analysis
Sludge samples from two sewers were analyzed for physical characteristics such as pH, ash con-
tent, humidity and chemical components including total nitrogen, total phosphorus, and heavy metal
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Ha, T. D. et al.
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concentrations including zinc (Zn), copper (Cu), Cadmium (Cd), and lead (Pb). In addition, sludge
thickness along the sewers was also measured. For To Lich River sediments, heavy metals such as
arsenic (As), mercury (Hg), lead (Pb), chromium (Cr), cadmium (Cd), zinc (Zn) and copper (Cu)
were examined. Samples are analyzed in an accordance with Vietnamese standards (c.a. TCVN
4196:2012: Soils - Laboratory methods for determination of moisture and hydroscopic water amount;
TCVN 8467:2010 (ISO 20280:2007): Soil quality - Determination of arsenic in aqua regia soil ex-
tracts with electro thermal or hydride-generation atomic absorption spectrometry; TCVN 8246:2009
(EPA Method 7000B): Soil quality - Flame atomic absorption spectrophotometry; and TCVN 8882:
2011 (ISO 16772 : 2004): Soil quality - Determination of mercury in aqua regia soil extracts with
cold-vapour atomic spectrometry or cold - vapour atomic fluorescence spectrometry) [
16
–
19
]. The
samples were analyzed no later than eight days for total ash, and Hg. The preservation time for sludge
and sediment samples were less than four months for other heavy metals [
14
,
15
]. Each sample was
measured for at least three times.
2.3. Comparisons of sludge quality and national regulations
The results of the analysis were compared to Vietnamese environmental regulations on hazardous
thresholds in soils, aquatic life protection, and sludge reuse including QCVN 43:2012
/BTNMT-
National Technical Regulation on Sediment Quality, QCVN 50:2013
/BTNMT - National Technical
Regulation on Hazardous Thresholds for Sludge from Water Treatment Process and TCVN 03-MT:
2015
/BTNMT- National technical regulations on the allowable limits of heavy metals in the soils to
determine the hazardous level and assess the potential reuse [
20
–
23
].
3. Results and Discussion
3.1. Characteristics of sewage sludge and sediment in TLR basin
a. Characteristics of sewage sludge
The average humidity of TBT sewer in dry and rainy seasons (83.5% and 87%) are higher than
these values of TH sewer (81% and 84%). The ash content in the old urban areas was lower than that
in the new areas. In the new urban areas with ongoing key building sites, dust from anthropogenic
activities on the surface, together with wastewater from road washing, and constructing in dry season,
as well as with storm water in rainy season will be swept into the sewers. However, the flow rate of
wastewater in the drainage system in both rainy and dry seasons is insu
fficient to clean up sediment
according to the report from HDSC [
1
]. Consequently, it is essential to use mechanical measures to
remove the sludge deposited in the sewer.
Sludge from sewers contained low organic concentration and high heavy metal contents in both
seasons as shown in Table
1
. Those results were consistent with previous studies [
23
,
24
] on sewage
sludge in Hanoi.
Because most of the organic matters decompose in the onsite septic tanks, and gradually in the
sewer, the di
fferences in concentration of those substances between two seasons are not significant.
However, ash content in rainy season is slightly higher than that in dry season since surface dust is
swept by storm water into the sewers. For heavy metals, storm water is continuously added to the
sewer, thus, remove metals from the deposited sludge into water. Therefore, the concentration of trace
metals in sewage sludge is higher in dry season than in rainy season.
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Ha, T. D. et al.
/ Journal of Science and Technology in Civil Engineering
Table 1. Physical characteristics and heavy metal contents of sewage sludge from sewers in TLR Basin and
comparison with Vietnamese environmental regulations
pH
Humidity,
%
Ash
content,%
Zn,
mg·kg
−1
Cu,
mg·kg
−1
Pb,
mg·kg
−1
Cd,
mg·kg
−1
Dry
season
(1)
6.64±0.35 85.2±4.5
78.2±2.5
644±23
146.5±11.4 71.2±2.1
1.51±0.12
Rainy
season
(1)
6.52±0.27 84.7±3.9
79.6±3.1
598±23
127.3±12.5 69.5±1.7
1.46±0.11
Hazards
(2)
NA
NA
NA
5,000
NA
300
10
Agr.
(3)
NA
NA
NA
200
100
70
1.5
For.
(3)
NA
NA
NA
200
150
100
3
Com. and
Ser.
(3)
NA
NA
NA
250
200
200
5
Ind.
(3)
NA
NA
NA
250
300
300
10
(1)
Pooled data from sewers in both old and new urban areas.
(2)
Thresholds for toxics in Vietnamese standards for Hazard [
22
].
(3)
Acceptable value for sludge and soils to be reused as land for various purposes [
23
].
Arg. - Agricultural land, For. - Forestry land, Com. and Ser. - Commercial and Service land, and Ind. - Industrial
land, NA - not available.
b. Characteristics of TLR sediment
The concentration of heavy metals according to six parameters regulated in Vietnamese environ-
mental standards [
23
] is relatively high. Those concentrations decrease gradually in the order of Cr >
Zn > Pb > As > Cd > Hg in accordance with Report on feasibility study for Hanoi Drainage Project-
Phase 2 [
25
]. Chromium content is noticeably large, ranging from 156 to 158 mg·kg
−1
. However, the
concentration of heavy metals in the present study is lower than that reported in [
8
,
9
,
13
]. The di
ffer-
ence can be explained by the change in the nature of the refill of TLR sediment including rainwater
and wastewater from the sewers, and canals in the catchment. In the past few years, heavy metals
in wastewater must be treated before discharged into the city’s combined drainage network. In addi-
tion, sewerage sludge (from the drains, canals, and ditches) must be regularly dredged. Consequently,
the concentration of pollutants, including heavy metals, in wastewater and sediment is significantly
reduced and competent with those predicted in the previous report [
26
] (see Table
2
).
3.2. Assessment of potential hazards and reusability of drainage sludge from TLR basin
a. Potential hazards and reusability of sewage sludge
Heavy metal, including Zn, Pb, and Cd, as shown in Table
3
, was below the allowable limits of
hazards in the soils [
23
], thus, considered nontoxic. Regarding the reusability, sewage sludge is not
suitable for all of land use purposes due to exceeded concentration of Zn in both of dry and rainy
seasons. The reusability of other heavy metals di
ffers between two seasons. Particularly, Cu, Pb, and
Cd do not satisfy the thresholds for agricultural activities but can be reused for other types of land
use in dry season. In rainy season, those metals meet the permissible values for lands in forestry,
commerce and service, and industry.
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Ha, T. D. et al.
/ Journal of Science and Technology in Civil Engineering
Table 2. Concentration of heavy metals in sediment from sampling sites
Sampling site
Concentration (mg·kg
−1
)
As
Hg
Pb
Zn
Cr
Cd
S1
0.661
0.03
3.91
81.1
156.8
0.079
S2
0.659
0.03
4.07
81.2
157.5
0.077
S3
0.657
0.03
3.96
81.3
157.6
0.078
S4
0.661
0.03
4.12
81.3
157.6
0.076
S5
0.659
0.03
4.09
81.3
157.9
0.078
S6
0.659
0.03
4.16
81.3
157.7
0.081
S7
0.660
0.03
4.17
81.4
156.7
0.076
Mean ± SD
0.659±0.001
0.03±0.00
4.07±0.10
81.3±0.1
157.4±0.5
0.078 ± 0.002
Table 3. Comparisons of heavy metal concentrations in TLR sediment with permissible limits
in Vietnamese environmental standards
Value
Concentration (mg·kg
−1
)
As
Hg
Pb
Zn
Cr
Cd
This study,
Mean ± SD
0.659±0.001
0.03±0.00
4.07±0.10
81.3±0.1
157.4±0.5
0.078±0.002
Hazardous
Waste
Threshold [
20
]
40
4
300
5000
100
10
Hazardous
waste for
sludge from
Water
Treatment
Process [
22
]
40
4
300
5000
100
10
For aquatic life
preservation
[
21
]
17.0
0.5
91.3
315
90
3.5
Agr. [
23
]
200
NA
70
200
150
1.5
For. [
23
]
200
NA
100
200
200
3
Com. and
Ser. [
23
]
250
NA
200
300
250
5
Ind. [
23
]
250
NA
300
300
250
10
Arg. - Agricultural land, For. - Forestry land, Com. and Ser. - Commercial and Service land, and Ind. - Industrial land,
NA - not available.
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Ha, T. D. et al.
/ Journal of Science and Technology in Civil Engineering
b. Potential hazards and reusability of TLR sediment
To assess the risk of TLR sediment, we compared the result of sludge analysis with Vietnamese
standards for hazardous waste, sediment hazards to protect aquatic life in fresh water [
20
,
21
]. Among
analyzed metals, Chromium content exceeds the allowable values in both of those standards. How-
ever, if considering TLR sediment as the sludge from water treatment process to assess the hazard
threshold under the corresponding standard [
22
], the Cr(VI) composition should be evaluated. Ha et
al.
[
26
] showed that Cr(VI) ratio of total Cr in drainage sludge is extremely small. Marcussen et al.
[
9
] also agreed that Cr(VI) in TLR sediment is not significant since Cr is a
ffected by the reduction of
Fe(II) in pore water.
Due to deposition process in sewers and wastewater-receiving river, concentrations of some heavy
metals such as As, Zn, Pb, Cr. . . exceeded the threshold for freshwater sediment for aquatic life pro-
tection [
21
]. It is therefore necessary to remove the sediment from TLR.
Overall, the concentrations of heavy metals in TLR meet the requirements for land used, c.a.
agriculture, forestry, agriculture, forestry, service and commerce, and industry. This result is contrary
to the conclusion of Ingvertsen et al. [
13
] when they claimed that the To Lich River sediment was not
suitable for any purpose of land use. However, for Cr, its content in sediment exceeds the allowable
limit for agricultural land.
3.3. Proposals for suitable sludge management
Yen So landfill site is the only place to receive sludge from the sewerage network and wastewater
treatment plants in Hanoi. The amount of sludge dredged is expected to increase in the upcoming
years, thus, leading to the overload and pollution for that site. Therefore, it is necessary to search for
appropriate management solutions for the sludge from the urban drainage system of Hanoi.
Analysis results of heavy metal content in dredged sediment from TLR show that this type of
sludge is not hazardous waste which should be managed as other solid wastes. With low content of
heavy metals and humidity (75-80%), dried sludge can be used to level the construction or to grow
some suitable agricultural crops. Additionally, drainage sludge contains high concentration of N and
P, thus, suitable for fertilizers [
24
]. In case of reuse as fertilizer or soil for agricultural purposes, heavy
metal components must be treated by chemical or biological methods on the constructed wetland
[
26
,
27
].
Humidity of drainage sludge is relatively high, thus, di
fficult to transport and easy to contaminate
surrounding environment. Ha et al. (2012) [
28
] proposed the use of a hydraulic cylinder at dredging
points to reach sludge humidity of 80-82% before sludge is transported. Despite of high nutrient
content, sewage sludge is di
fficult to reuse as fertilizer due to the limited organic contents and surplus
heavy metal. The sludge needs to be dried to a level below 60% on a sludge drying bed before
transported [
26
,
29
].
Direct dumping on landfill sites has been reduced to less than 1% of the whole waste sludge
accumulation [
30
]. To dehydrate the dredge sludge, the most economical solution is to dry the sludge
drying bed by evaporation and filtration [
31
]. However, this natural method is susceptible to odors
and high concentration of heavy metals, and suspended solids, leading to environmental pollution for
surrounding areas.
An e
ffective solution for drying and separating heavy metals in sludge is to stabilize sludge in the
wetland site. Pollutants in sludge are treated by microorganisms on the roots of rush family trees.
Nutrients, such as nitrogen and phosphorus, are converted into plant biomass. Heavy metals are
deposited in plant biomass due to root absorption. In the anoxic sludge layer below the wetland, the
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Ha, T. D. et al.
/ Journal of Science and Technology in Civil Engineering
activities of microorganisms in sulfate reduction process create low pH environment, generate sulfide
ion and convert heavy metals into dissolved forms [
26
]. The content of heavy metals in sludge, thus,
reduces and satisfies requirements of agricultural land or other types of land used for other purposes
in accordance with Vietnamese regulations. The sludge leachate is filtered through the limestone
underneath and pumped into the reservoir. By adding alkalis, e.g. lime or soda, to raise pH, metal
hydroxides are generated and precipitated ready to be reuse or dispose of heavy metals [
26
].
Additionally, organic components are decomposed and mineralized, leading to the high content
of inorganic matters in drainage sludge. Sludge from sewers, canals and the wastewater-receiving
river, hence, can be reused as construction material or artificial sand [
32
]. Sewage sludge contains
high contents of construction materials and silt so it can be reused as a source of raw materials for
the production of bricks and tiles. Besides, sludge generated from water purification process can
contribute to ceramic production [
33
]. The approach of reused sludge as construction materials is
predicted as suitable for drainage sludge management in a city with rapid urbanization process like
Hanoi.
4. Conclusions
Sewage sludge and wastewater-receiving river sediment di
ffers in physical characteristics and
chemical compositions depending on the location of sewers in urban areas, types of canals, and time
of dredge in rainy and dry seasons. Sludge generated from drainage network of a city under con-
struction like Hanoi has high humidity and inorganic content. Although heavy metals in sewage
sludge and river sediment exceeds national standards for sediment to protect fresh aquatic life, they
are below standards for hazardous wastes. Therefore, sewage sludge and TLR sediment can be reused
as industrial, commercial, and service land. In case the sludge is reused as fertilizer or agricultural
soil, heavy metal concentration should be lessened. Due to low organic content, sewage sludge can
be dried to produce construction materials instead of direct disposal on the landfill site [
31
]. These
are reasonable solutions for dredged sludge to ensure stable operation of Yen So landfill site and to
minimize the potential environmental pollution in the surrounding area.
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