Table S3: Solvents, native and mass-labelled analytical standards and gases used in this study.
Substance
|
Acronym
|
Purity
|
Supplier
|
2-Perfluorohexyl-(13C2)-ethanol
|
13C 6:2 FTOH
|
> 98
|
Wellington, Guelph, Canada
|
2-Perfluorooctyl-(13C2)-ethanol
|
13C 8:2 FTOH
|
> 98
|
Wellington, Guelph, Canada
|
2-Perfluorodecyl-(13C2)-ethanol
|
13C 10:2 FTOH
|
> 98
|
Wellington, Guelph, Canada
|
methyl-D3-perfluorooctane sulfonamide
|
MeFOSA D3
|
> 98
|
Wellington, Guelph, Canada
|
ethyl-D5-perfluorooctane sulfonamide
|
EtFOSA D5
|
> 98
|
Wellington, Guelph, Canada
|
methyl-D7-perfluorooctane sulfonamido ethanol
|
MeFOSE D7
|
> 98
|
Wellington, Guelph, Canada
|
ethyl-D9-perfluorooctane sulfonamidoethanol
|
MeFOSE D9
|
> 98
|
Wellington, Guelph, Canada
|
perfluoro-(13C4)-butanoic acid
|
13C PFBA
|
>98
|
Wellington, Guelph, Canada
|
perfluoro-(13C4)-hexanoic acid
|
13C PFHxA
|
>98
|
Wellington, Guelph, Canada
|
perfluoro-(13C4)-octanoic acid
|
13C PFOA
|
>98
|
Wellington, Guelph, Canada
|
perfluoro-(13C4)-nonanoic acid
|
13C PFNA
|
>98
|
Wellington, Guelph, Canada
|
perfluoro-(13C4)-decanoic acid
|
13C PFDA
|
>98
|
Wellington, Guelph, Canada
|
perfluoro-(13C4)-undecanoic acid
|
13C PFUnDA
|
>98
|
Wellington, Guelph, Canada
|
perfluoro-(13C4)-dodecanoic acid
|
13C PFDoA
|
>98
|
Wellington, Guelph, Canada
|
sodium perfluoro-(18O2)-hexane sulfonate
|
18O2-PFHxS
|
>99
|
Wellington, Guelph, Canada
|
sodium perfluoro-(13C4)-octane sulfonate
|
13C-PFOS
|
>98
|
Wellington, Guelph, Canada
|
sodium perfluoro-(13C4)-octane sulfinate
|
13C-PFOSi
|
~90
|
Wellington, Guelph, Canada
|
hexachlorobenzene 13C6
|
13C HCB
|
97
|
Dr. Ehrenstorfer, Augsburg, Germany
|
1,3,5-trichlorobenzene D3
|
TCB D3
|
98
|
Aldrich, Munich, Germany
|
perfluorooctane sulfonamido-D5-acetic acid
|
EtFOSAA D5
|
>98
|
Wellington, Guelph, Canada
|
perfluorobutyl ethanol
|
4:2 FTOH
|
97
|
Aldrich, Munich, Germany
|
perfluorohexyl ethanol
|
6:2 FTOH
|
97
|
Lancaster Synthesis, Frankfurt, Germany
|
perfluorooctyl ethanol
|
8:2 FTOH
|
97
|
Lancaster Synthesis, Frankfurt, Germany
|
perfluorodecyl ethanol
|
10:2 FTOH
|
97
|
Lancaster Synthesis, Frankfurt, Germany
|
perfluorododecyl ethanol
|
12:2 FTOH
|
-
|
Donated by Lancaster University, UK
|
perfluorohexyl ethylacylate
|
6:2 FTA
|
97
|
Aldrich, Munich, Germany
|
perfluorooctyl ethylacylate
|
8:2 FTA
|
97
|
Fluorochem, Old Glossop, UK
|
perfluorodecyl ethylacylate
|
10:2 FTA
|
97
|
Fluorochem, Old Glossop, UK
|
n-methyl perfluorobutane sulfonamide
|
MeFBSA
|
-
|
donated by 3M, Germany
|
n-methyl perfluorooctane sulfonamide
|
MeFOSA
|
-
|
donated by 3M, Germany
|
n-ethyl perfluorooctane sulfonamide
|
EtFOSA
|
95
|
ABCR, Karlsruhe, Germany
|
perfluorooctane sulfonamide
|
PFOSA
|
-
|
donated by 3M, USA
|
dimethylperfluoroocatane sulfonamide
|
Me2FOSA
|
98
|
Wellington, Guelph, Canada
|
n-methyl perfluorobutane sulfonamido ethanol
|
MeFBSE
|
-
|
donated by 3M, USA
|
n-methyl perfluorooctane sulfonamido ethanol
|
MeFOSE
|
-
|
donated by 3M, USA
|
n-ethyl perfluorooctane sulfonamido ethanol
|
EtFOSE
|
-
|
donated by Toronto University, Canada
|
Perfluorobutanoic acid
|
PFBA
|
99
|
ABCR, Karlsruhe, Germany
|
perfluoropentanoic acid
|
PFPA
|
98
|
Alfa Aesar, Karlsruhe, Germany
|
Perfluorohexanoic acid
|
PFHxA
|
98
|
ABCR, Karlsruhe, Germany
|
perfluoroheptanoic acid
|
PFHpA
|
98
|
Lancaster, Frankfurt, Germany
|
Table S2 cont.
Substance
|
Acronym
|
Purity
|
Supplier
|
perfluorooctanoic acid
|
PFOA
|
95
|
Lancaster, Frankfurt, Germany
|
perfluorooctanoic acid
|
PFOA
|
95
|
Lancaster, Frankfurt, Germany
|
Perfluorononanoic acid
|
PFNA
|
98
|
Alfa Aesar, Karlsruhe, Germany
|
Perfluorodecanoic acid
|
PFDA
|
98
|
ABCR, Karlsruhe, Germany
|
perfluoroundecanoic acid
|
PFUnDA
|
96
|
ABCR, Karlsruhe, Germany
|
perfluorododecanoic acid
|
PFDoDA
|
96
|
Alfa Aesar, Karlsruhe, Germany
|
2,4,4'-Tribromo[13C6]diphenyl ether
|
MBDE28
|
>98
|
Wellington, Guelph, Canada
|
2,2',4,4'-Tetrabromo[13C6]diphenyl ether
|
MBDE47
|
>98
|
Wellington, Guelph, Canada
|
2,2',4,4',5-Pentabromo[13C6]diphenyl ether
|
MBDE99
|
>98
|
Wellington, Guelph, Canada
|
2,2',4,4',5,5'-Hexabromo[13C6]diphenyl ether
|
MBDE153
|
>98
|
Wellington, Guelph, Canada
|
2,2',3,4,4',5',6-Heptabromo[13C6]diphenyl ether
|
MBDE183
|
>98
|
Wellington, Guelph, Canada
|
Decabromo[13C6]diphenyl ether
|
MBDE209
|
>98
|
Wellington Guelph, Canada
|
2,4,4'-Tribromodiphenyl ether
|
BDE28
|
>98
|
Wellington, Guelph, Canada
|
2,2',4,4'-Tetrabromodiphenyl ether
|
BDE47
|
>98
|
Wellington, Guelph, Canada
|
2,2',4,4',5-Pentabromodiphenyl ether
|
BDE99
|
>98
|
Wellington , Guelph, Canada
|
2,2',4,4',6-Pentabromodiphenyl ether
|
BDE100
|
>98
|
Wellington , Guelph, Canada
|
2,2',4,4',5,5'-Hexabromodiphenyl ether
|
BDE153
|
>98
|
Wellington , Guelph, Canada
|
2,2',4,4',5,6'-Hexabromodiphenyl ether
|
BDE154
|
>98
|
Wellington , Guelph, Canada
|
2,2',3,4,4',5',6-Heptabromodiphenyl ether
|
BDE183
|
>98
|
Wellington , Guelph, Canada
|
Decabromodiphenyl ether
|
BDE209
|
>98
|
Wellington , Guelph, Canada
|
Fluoranthene-d10
|
Fluoranthene D10
|
>98
|
Dr. Ehrenstorfer, Augsburg, Germany
|
1-tert-Buthyl-3,5-dimethyl-2,4,6-trinitrobenzene
|
MX
|
>99
|
Ehrenstorfer, Augsburg, Germany
|
1-tert.-butyl-3,5-dimethyl-2,6-dinitro-4-acetyl-benzene
|
MK
|
98
|
Dr. Ehrenstorfer, Augsburg, Germany
|
Musk xylene D15
|
MX D15
|
>97
|
Dr. Ehrenstorfer, Augsburg, Germany
|
7-Acetyl-1,1,3,4,4,6-hexamethyl-1,2,3,4-Tetrahydronaphthalene
|
AHTN D3
|
99
|
Dr. Ehrenstorfer, Augsburg, Germany
|
7-Acetyl-1,1,3,4,4,6-hexamethyl-1,2,3,4- Tetrahydronaphthalene
|
AHTN
|
98
|
Dr. Ehrenstorfer, Augsburg, Germany
|
5-Acetyl-1,1,2,6-tetrametyl-3-isopropyl-dihydroindene
|
ATII
|
98
|
Dr. Ehrenstorfer, Augsburg, Germany
|
4-acetyl-1,1-dimethyl-6-tert-butylindane
|
ADBI
|
98
|
Dr. Ehrenstorfer, Augsburg, Germany
|
6-acetyl-1,1,2,3,3,5-hexamethylindane
|
AHMI
|
98
|
Dr. Ehrenstorfer, Augsburg, Germany
|
1,3,4,6,7,8-Hexahydro-4,6,6,7,8,8-hexamethylcyclopenta-(γ)-2-benzopyran
|
HHCB
|
51
|
Dr. Ehrenstorfer, Augsburg, Germany
|
hexane
|
-
|
picograde
|
Promochem, Wesel, Germany
|
ethyl acetate
|
-
|
picograde
|
Promochem, Wesel, Germany
|
acetone
|
-
|
picograde
|
Promochem, Wesel, Germany
|
methyl-tert-butylether
|
MTBE
|
picograde
|
Promochem, Wesel, Germany
|
methanol
|
MeOH
|
residual analysis
|
J.T. Baker, Griesheim, Germany
|
Helium
|
-
|
5.0
|
Air Liquide, Krefeld, Germany
|
nitrogen
|
-
|
5.0
|
Air Liquide, Krefeld, Germany
|
methane
|
-
|
5.0
|
Air Liquide, Krefeld, Germany
|
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